Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh     

Jerome Métral  Laurent Charlet  Sara Bureau  Sukumar Basu Mallik  Sudipta Chakraborty  Kazi M Ahmed  MW Rahman  Zhongqi Cheng  Alexander van Geen 《Geochemical transactions》2008,9(1):1

Background  

The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh.  相似文献   

Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances   总被引：2，自引：2，他引：0  

Alain Cocherie  Michle Robert 《Gondwana Research》2008,14(4):597

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.  相似文献   

Numerical simulation of a stratigraphic model     

Véronique Gervais  Roland Masson 《Computational Geosciences》2008,12(2):163-179

A multi-lithology diffusive stratigraphic model is considered, which simulates at large scales in space and time the infill of sedimentary basins governed by the interaction between tectonics displacements, eustatic variations, sediment supply, and sediment transport laws. The model accounts for the mass conservation of each sediment lithology resulting in a mixed parabolic, hyperbolic system of partial differential equations (PDEs) for the lithology concentrations and the sediment thickness. It also takes into account a limit on the rock alteration velocity modeled as a unilaterality constraint. To obtain a robust, fast, and accurate simulation, fully and semi-implicit finite volume discre tization schemes are derived for which the existence of stable solutions is proved. Then, the set of nonlinear equations is solved using a Newton algorithm adapted to the unilaterality constraint, and preconditioning strategies are defined for the solution of the linear system at each Newton iteration. They are based on an algebraic approximate decoupling of the sediment thickness and the concentration variables as well as on a proper preconditioning of each variable. These algorithms are studied and compared in terms of robustness, scalability, and efficiency on two real basin test cases.  相似文献   

Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain   总被引：1，自引：0，他引：1  

Elena Giménez Forcada  Ignacio Morell Evangelista 《Hydrogeology Journal》2008,16(3):547-557

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.  相似文献   

The Meso-Cenozoic thermo-tectonic evolution of the Eastern Pyrenees: an <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar fission track and (U–Th)/He thermochronological study of the Canigou and Mont-Louis massifs     

O. Maurel  P. Moniè  R. Pik  N. Arnaud  M. Brunel  M. Jolivet 《International Journal of Earth Sciences》2008,97(3):565-584

Vertical displacements on the SW–NE Têt fault (Eastern Pyrenees Axial Zone, France), which separates the Variscan Canigou-Carança and Mont-Louis massifs, were constrained using a thermochronologic multi-method approach. ⁴⁰Ar/³⁹Ar data from the granitic Mont-Louis massif record its Variscan cooling history and reveal no ages younger than Early Cretaceous, while the Canigou-Carança gneiss massif records systematically younger ⁴⁰Ar/³⁹Ar ages. These younger ⁴⁰Ar/³⁹Ar ages in the Canigou-Carança gneiss massif are the result of partial to total rejuvenation of argon isotopic systems related to a thermal flow coeval with the Cretaceous HT-BP metamorphism in the North Pyrenean Zone. Only the deepest rocks from the Canigou-Carança suffered this extensive Mid-Cretaceous thermal overprint probably due to differential burial around 4 km at that time. The post Mid-Cretaceous vertical displacements along the Têt fault are recorded by “low” temperature thermochronology using K-feldspar ⁴⁰Ar/³⁹Ar, zircon and apatite fission track and (U–Th)/He datings. The Mont-Louis granite samples experienced a long period of protracted cooling reflecting a lack of thermo-tectonic activity in this area from Late Palaeozoic to Early Cenozoic, followed by cooling from 55–60 Ma to Late Eocene at a mean rate of 15–20°C/Ma in the final stage. This cooling stage corresponds to Têt fault reactivation with a reversed component, promoting exhumation of the Mont-Louis roof zone contemporaneously with the south-vergent Pyrenean thrusting. In the Canigou-Carança massif, the main cooling event occurred from 32 to 18 Ma at a maximum rate of 30°C/Ma during Early Oligocene followed by a more moderate rate of 3°C/Ma from Late Oligocene to Early Burdigalian, coeval with the normal reactivation of the Têt fault in brittle conditions that accommodated the final exhumation of the massif during the opening of the Gulf of Lion.  相似文献   

New age constraints on emplacement of the Cévenol granitoids, South French Massif Central     

Stéphanie Brichau  Jean-Patrick Respaut  Patrick Monié 《International Journal of Earth Sciences》2008,97(4):725-738

During the development of the Variscan orogeny, large amounts of granitic melt were produced, giving rise to the intrusion of granitoids at different structural levels. Despite numerous studies, ages available from previous work on the Cévennes granites remain largely imprecise. In order to better constrain the age and emplacement mode of these granites, we have combined U–Pb dating on monazites and zircons and ⁴⁰Ar/³⁹Ar dating on biotites with petrological observations, major element chemical analysis and SEM zircon imaging on five samples from the Aigoual–St Guiral–Liron and Mont Lozère granitic massifs. The results revealed that granitic intrusions and cooling in Southern Cévennes occurred in a short time span at ∼306 Ma after the main episode of regional metamorphism. Petrological and chemical data suggest that they result from a mixing between mantle-derived basic magmas (lamprophyres) and lower crust acid magmas. At a regional scale the production of these melts occurred at the end of crustal thickening induced by nappe stacking, at the same time as the late anatectic events recorded further north in the Velay dome and the granulite facies metamorphism recorded in metasedimentary granulite enclaves brought up by Tertiary volcanoes of the Velay area (Bournac).  相似文献   

Inner part observation of theβ pictoris disk     

R. Ferlet  A. Lecavelier Des Etangs  G. Perrin  A. Vidal-Madjar  F. Sèvre  F. Colas  J. E. Arlot  C. Buil  H. Beust  A. M. Lagrange-Henri  J. Lecacheux  M. Deleuil  C. Gry 《Astrophysics and Space Science》1994,212(1-2):173-180

The inner regions of the circumstellar disk around Pictoris might be dust-free due to a possible planet which may have cleared up dust particles. We present a new observational technique based on the use of an anti-blooming CCD in order to directly image this zone. The structure of the disk is revealed down to 2 arcsec from the star (30 AU). We show that the Pic disk brightness is neutral inV, R, andI _C , but drops down when going inward inB, possibly related to a change in the dust composition. Also, a slight disk asymmetry is present but inverted from the outer to the inner zones.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.  相似文献   

Phase differences between irradiance and velocity low degree solar acoustic modes revisited     

A. Jiménez 《Solar physics》1994,152(1):319-319

Since 1984, simultaneous observations of irradiance and velocity solar acoustic modes, have been carried out by several authors in order to measure the phase difference between irradiance and velocity modes. Following the earliest observations with stratospheric balloon (Frolich and van Der Raay, 1984), a two ground-based stations (Tenerife and Baja California) were established (Jimenez et al, 1990) obtaining coherence results in the frequency range from 2.5 mHz to 4.3 mHz. These phase differences between irradiance and velocity solar acoustic modes are interpreted in terms of the non-adiabatic behaviour of the solar atmosphere. In 1988 the IPHIR (Frolich et al, 1988) instrument flown on the PHOBOS-2 mission to Mars and measured the solar irradiance during 150 consecutive days. The best velocity observations obtained in Tenerife for this period were compared with IPHIR data to compute the phase differences (Schrijver et al, 1991). The final conclusion is that good agreement is attained between space quadsi-space and ground observations which yield a phase diffenrece of about -125 degrees in the frequency range 2.5 mHz to 4.2 mHz, with a slight increase suggested by the data running up to 4.6 mHz.  相似文献   

Generalized Lyapunov exponents indicators in Hamiltonian dynamics: An application to a double star system     

E. Lohinger  C. Froeschlé  R. Dvorak 《Celestial Mechanics and Dynamical Astronomy》1993,56(1-2):315-322

The Lyapunov characteristic numbers (LCNs) which are defined as the mean value of the distribution of the local variations of the tangent vectors to the flow (=ln _k ⁱ ) (see Froeschlé, 1984) have been found to be sensitive indicators of stochasticity. So we computed the distribution of these local variations and determined the moments of higher order for the integrable and stochastic regions in a binary star system with =0.5.  相似文献   

Chemical abundance behavior of type I planetary nebulae     

M. Faúndez-Abans  J. L. Jiménez O 《Astrophysics and Space Science》1993,207(1):47-53

In this work 13 Planetary Nebulae have been classified as Type I according to Peimbert's criteria (Peimbert, 1978). These objects have been added to a previous sample (Maciel and Faúndez-Abans, 1985) and diagrams of O/H versus N/H, S/H, Ne/H and Ar/H, as well as N/H versus S/H, Ne/H and Ar/H have been drawn. All of them exhibit a tendency for linear correlation; moreover, the behavior of O and N versus Ar and S are very similar, with approximately the same slope. When the excitation class parameter was included in the diagrams, no clear tendency can be discerned, for any class.  相似文献